1,Introduction 介紹 The mechanical properties of particulates-filled polymers are significantly influenced by interfacial interactions, which depend on the interfacial compatibility and interfacial adhesion between the particulates and the matrix (Demjén et al., 1998). 粒子填充聚合物的力學性能受到界面相互作用的顯著影響，而界面相互作用又取決于界面相容性和顆粒與基體界面結合強度（Demjén 等 ，1998）。 There is a growing interest to study the interface of CaCO3 particles-filled polymer composites due to the particle aggregation induced by increase of surface free energy of nano-CaCO3 particles. Nano-CaCO3 particles are usually modified by low-molecule organics such as aliphatic acid (or their salt), titanate or aluminate coupling agents, and are then used as fillers added to polymer matrix to improve the mechanical properties of the composites (Ichazo et al., 1999; Liu et al., 2002; Zeng et al., 2002a & b;Qu et al., 2001; Luo et al, 1999). 人們越來越關心對碳酸鈣粒子填充高分子復合材料表面因納米碳酸鈣粒子的表面自由能的增加而誘發的粒子聚合的研究。納米碳酸鈣粒子通常由低分子有機物如脂肪酸（或其鹽），鈦酸酯偶聯劑或鋁酸酯偶聯劑改性，然后被當作填充物加入到聚合物基體用來提高復合材料的物理性能。(Ichazo 等, 1999; Liu 等, 2002; Zeng 等., 2002a & b; Qu 等., 2001; Luo 等, 1999). Polymer alloys with superior mechanical properties can be prepared by blending two or more polymers with similar polarity and good compatibility. Composite systems containing inorganic particles graft-modified by polymer usually have good compatibility with polymer matrix. 具有優秀的機械性能的高分子聚合物合金可以通過混合兩種或兩種以上具有相似極性和良好兼容性的聚合物制備。包含由高分子聚合物枝接改性的無機粒子通常對聚合物基體有良好的兼容性。 Much research has been carried out (Liu et al., 2001; Luna-Xavier et al, 2002; Shim et al., 2002; Yang & Dan, 2003; Meneghetti & Qutubuddin, 2001; Lee & Seul, 2002; Wu et al., 2002) in the polymerization of monomer together with inorganic particles to make composites, such as SiO2/PS, ZnO/PMMA and clay/PMMA using methods such as emulsion polymerization and radiation polymerization. 很多關于單體和無機粒子通過聚合作用形成復合材料的研究 (Liu等, 2001; Luna-Xavier 等2002; Shim 等, 2002; Yang & Dan, 2003; Meneghetti & Qutubuddin, 2001; Lee & Seul, 2002; Wu 等2002) 被完成，像二氧化硅/聚苯乙烯, 氧化鋅/PMMA和粘土/PMMA 等通過乳液聚合作用或輻照聚合等方法實現。、 Godard et al. (1993) studied the interfacial interaction of PBA-g-CaCO3/PS composites, and found that the tensile strength of these composites changed with interfacial adhesion and matrix-particle stress transfer. Qian et al. (2002) demonstrated that the toughness of SiO2/PC composites prepared by emulsion polymerization was markedly improved if PMMA-g-SiO2 were used as fillers. Wu et al.(2002) indicated that the interfacial adhesion, toughness and intension of nano-SiO2/PP composites were improved if SiO2 nanoparticles was graft-modified with PS and PEA by radiation polymerization. Godard等(1993)研究 PBA-g-CaCO3/PS復合材料的界面相互作用，并發現這些復合材料的拉伸強度隨著表面結合強度和基體-粒子的應力轉移的變化而變化。Qian 等(2002)證明了由乳液聚合作用制備的SiO2/PC復合材料的韌性在使用PMMA-g-SiO2做填料時會明顯提高穿訂扁寡壯干憋吮鉑經。Wu 等.(2002)指出， 如果Sio2納米粒子通過輻照聚合法由PS和PEA枝接改性的話，納米SiO2/PP (二氧化硅/聚苯乙烯)復合材料的表面結合強度，韌性和強度將會顯著提高， 注 1，文獻中et al的翻譯。英文百科全書的解釋 adv 1: used as an abbreviation of `et alii' (masculine plural) or `et aliae' (feminine plural) or `et alia' (neutral plural) when referring to a number of people [syn: et al., and others] 2: used as an abbreviation of `et alibi' when referring to other occurrences in a text [syn: et al., and elsewhere] et al abbr. (Lat) 以及其他人，等人 人工翻譯，仔細求證，如有幫助，請采納。謝謝。

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